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Question about Eutectic and Azeotropic Mixtures

Chemistry

Originais Teachy

Eutectic and Azeotropic Mixtures

Medium

(Originais Teachy 2024) - Question Medium of Chemistry

During an experiment in a laboratory, a sample containing chloroform (CHCl3) and acetone (C3H6O), two liquid substances miscible in any proportion, was subjected to gradual heating. In order to identify whether the mixture exhibits eutectic, azeotropic, or conventional behavior, the temperature variations and vapor pressures of the mixture in different states were recorded. Analyzing a graph that relates temperature to the vapor pressure of the mixture, it is observed that at 60°C, the measured vapor pressure is lower than the expected pressure for a conventional mixture with the same proportions of pure chloroform and acetone. Considering the properties of eutectic, azeotropic, and conventional mixtures, and the expected behavior of vapor pressures for each type of mixture, determine which of these behaviors the chloroform and acetone mixture exhibits, and explain your choice based on the phenomenon of freezing point depression characteristic of eutectic and azeotropic mixtures.
a.
The chloroform and acetone mixture exhibits a behavior that suggests it is eutectic or azeotropic, but the exact classification cannot be determined without more information.
b.
The chloroform and acetone mixture exhibits eutectic behavior, which is evidenced by the constant boiling point observed in the graph.
c.
Based on the vapor pressure variation, it can be stated that the chloroform and acetone mixture is an azeotropic mixture, without a doubt.
d.
The chloroform and acetone mixture follows the behavior of a conventional mixture, as the vapor pressure is equal to the expected pressure for a mixture of fixed composition.
e.
The comparison of vapor pressure indicates that the chloroform and acetone mixture is an example of an azeotropic mixture, characterized by a single boiling temperature.

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